Tbsdirect.co.uk

REVISION DATE: 25-11-2004 SAFETY DATA SHEET
RONSEAL TOTAL WOOD PRESERVER - CLEAR
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/
UNDERTAKING
PRODUCT NAME
RONSEAL TOTAL WOOD PRESERVER - CLEAR
PRODUCT NO.
INTERNAL ID
Commodity Code 380820 50 00
SYNONYMS, TRADE NAMES
(SPN 10556)
For use only as a wood preservative.
Ronseal Ireland Ltd.
Ronseal Ltd
Oak House, Leopardstown Office Park,
Dublin 18.
Sheffield S35 2YP
00 353 1 294 4009
00 353 1 294 4016
[email protected]
Ronseal Ireland:- Tel (00) 353 1 294 4009 Fax (00) 353 1 294 4016
For UK emergency enquiries:- Tel +44 (0) 114 246 7171 Fax +44 (0) 114 245 5629
2 COMPOSITION/INFORMATION ON INGREDIENTS
Xn;R22. N;R50/53. R43.
WHITE SPIRIT
50-100% Xn;R65. N;R51/53. R10,R66.
The Full Text for all R-Phrases are Displayed in Section 16
COMPOSITION COMMENTS
Contains Permethrin 0.093% ww/w (0.725g/l) Contains Propiconazole 0.50% w/w (3.91 g/l); May produce an allergic
reaction Contains White Spirit.
3 HAZARDS IDENTIFICATION
Flammable. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Repeated
exposure may cause skin dryness or cracking. Harmful: may cause lung damage if swallowed.
CLASSIFICATION
Xn;R65. N;R51/53. R10,R66.
4 FIRST-AID MEASURES
GENERAL INFORMATION
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious
person.
INHALATION
Remove to fresh air, keep the patient warm and at rest. If breathing has stopped administer artificial respiration. Give
nothing by mouth. If unconscious, place in the recovery position and seek medical advice.
INGESTION
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
SKIN CONTACT
Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT
use solvents or thinners. Seek medical advice if any irritation persists.
REVISION DATE: 25-11-2004 RONSEAL TOTAL WOOD PRESERVER - CLEAR
EYE CONTACT
Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids
apart, and seek medical advice.
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Fire can be extinguished using: alcohol resistant foam, carbon dioxide (CO2), powder, water spray/ mist. Do not use water
jet.
SPECIAL FIRE FIGHTING PROCEDURES
Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to
decomposition products may be hazardous to health. Appropriate self-contained breathing apparatus may be required.
Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or
watercourses.
6 ACCIDENTAL RELEASE MEASURES
SPILL CLEAN UP METHODS
Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to
protective measures listed in Section 7 and 8. Contain and collect spillage with non-combustible absorbent materials, e.g.
sand, earth or vermiculite, and place in a suitable container for disposal in accordance with the waste regulations (see
Section 13). Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers,
immediately contact the local water company; in the case of contamination of streams, rivers or lakes, the relevant
environment agency.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Keep away from heat, sparks and open flame. Avoid skin and eye contact. Avoid breathing dust. Smoking, eating and
drinking should be prohibited in areas of storage and use. Wear suitable protective clothing and gloves. Avoid inhalation of
vapours and spray mists. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above
accepted level. Do not contaminate foodstuffs, eating utensils or food contact surfaces. Cover water storage tanks before
application. Remove and cover all fish tanks and bowls before application. Do not contaminate ground, waterbodies or
watercourses with chemical or used container. Wash hands and exposed skin before meals and after use. Wash any
contamination from skin and eyes immediately Use only in well ventilated areas. Ventilate treated areas thoroughly after
application. Unprotected persons and animals should be kept away from treated areas for 48 hours or until surfaces are dry
. Until dry, treated areas can pose a fire risk. This material and its container must be disposed of in a safe way.
For additional guidance refer to Safety Phrases shown in Section 15
For Occupational Exposure Controls, refer to Section 8.
The Manual Handling Operations Regulations may apply to the handling of containers/packages of this product.
STORAGE PRECAUTIONS
Observe the label precautions. Store between 5°C and 25°C. Keep in a cool, dry, well ventilated place, away from sources
of heat, ignition and direct sunlight. No smoking. Keep containers tightly closed. Keep only in original container. Keep out
of reach of children. Keep in a safe place. Keep away from food, drink and animal feeding stuffs.
The principles contained in the HSE Guidance Note: Storage of Packaged Dangerous Substances, should be observed
when storing this product.
To avoid the risk of spillage, always store and transport in a secure and upright position.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
LT - mg/m3
ST - mg/m3
WHITE SPIRIT
350 mg/m3
INGREDIENT COMMENTS
SUP = Supplier's recommendation.
ENGINEERING MEASURES
Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent
vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn.
RESPIRATORY EQUIPMENT
If exposure to hazardous substances identified above cannot be controlled by the provision of local exhaust ventilation and
good general extraction, suitable respiratory protective equipment should be worn.
REVISION DATE: 25-11-2004 RONSEAL TOTAL WOOD PRESERVER - CLEAR
HAND PROTECTION
Use protective gloves made of: Rubber, neoprene or PVC.
EYE PROTECTION
Eye protection designed to protect against liquid splashes should be worn.
OTHER PROTECTION
Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed
and the skin washed with soap and water or a proprietary skin cleaner.
All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous
substances must be selected to meet the requirements of the COSHH Regulations.
9 PHYSICAL AND CHEMICAL PROPERTIES
Very low viscosity liquid.
Characteristic solvent type.
Immiscible with water
FLASH POINT (°C)
41 CC (Closed cup).
10 STABILITY AND REACTIVITY
STABILITY
Stable if stored under recommended storage and handling conditions.
CONDITIONS TO AVOID
Keep away from oxidising agents and strongly alkaline and strongly acidic materials.
HAZARDOUS DECOMPOSITION PRODUCTS
In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and alcohols may be
produced.
11 TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION
No data recorded.
Exposure to organic solvent vapours in excess of the stated occupational exposure limit may result in adverse health
effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the kidney, liver and
central nervous systems. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and
in extreme cases loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin.
Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic
contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage.
Contains Propiconazole. May produce an allergic reaction.
INGESTION
If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
12 ECOLOGICAL INFORMATION
ECOTOXICITY
Dangerous for the environment: May cause long-term adverse effects in the aquatic environment. Avoid release to the
environment. Refer to special instructions / safety data sheets. Do not contaminate ground, waterbodies or watercourses
with chemicals or used containers. Avoid all contact with plant life. Obtain specialist advice before using on buildings or
structures known to be inhabited by bats. Do not use on beehives or beekeeping equipment.
DEGRADABILITY
There is no data available on the product itself.
ACUTE FISH TOXICITY
There is no data available on the product itself.
WATER HAZARD CLASSIFICATION
There is no data available on the product itself. The product should not be allowed to enter drains or watercourses, or be
deposited where it can affect ground or surface waters.
13 DISPOSAL CONSIDERATIONS
REVISION DATE: 25-11-2004 RONSEAL TOTAL WOOD PRESERVER - CLEAR
DISPOSAL METHODS
Do not allow into drains or watercourses, or dispose of where ground or surface waters may be affected. Wastes, including
emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the
Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should
be obtained from the Waste Regulation Authority whether the Special Waste Regulations apply.
14 TRANSPORT INFORMATION
Transport within user's premises: always transport in closed containers that are upright and
secure. Ensure that person's transporting the product know what to do in an accident or
spillage.
Limited Quantity concessions may apply to the carriage of this product.
PROPER SHIPPING NAME
WOOD PRESERVATIVES, LIQUID
UN NO. ROAD
ADR CLASS
Class 3: Flammable liquids.
ADR PACK GROUP
UN NO. SEA
IMDG CLASS
IMDG PACK GR.
15 REGULATORY INFORMATION
Dangerous for
the
environment
WHITE SPIRIT
RISK PHRASES
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Repeated exposure may cause skin dryness or cracking.
Harmful: may cause lung damage if swallowed.
Contains PROPICONAZOLE. May produce an allergic reaction.
Keep out of the reach of children
Keep away from food, drink and animal feeding stuffs.
Keep away from sources of ignition - No smoking.
Avoid contact with skin and eyes.
Do not empty into drains, dispose of this material and its container at
hazardous or special waste collection point.
This material and its container must be disposed of in a safe way.
Wear suitable protective clothing and gloves.
Use only in well-ventilated areas.
REVISION DATE: 25-11-2004 RONSEAL TOTAL WOOD PRESERVER - CLEAR
Avoid release to the environment. Refer to special instructions/safety data
sheets.
If swallowed, do not induce vomiting: seek medical advice immediately and
show this container or label.
UK REGULATORY REFERENCES
The information contained in this safety data sheet does not constitute the user's own assessment of workplace risks as
required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of
Substances Hazardous to Health Regulations apply to the use of this product at work.
The Manual Handling Operations Regulations
The Chemicals (Hazard Information and Packaging for Supply) Regulations.
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations.
European Agreement concerning the International Carriage of Dangerous Goods by Road [ADR]
EU DIRECTIVES
Dangerous Substance Directive 67/548 Dangerous Preparations Directive 88/379 Safety Data Sheet Directive 91/155
Biocidal Products Directive 98/8/EC
STATUTORY INSTRUMENTS
This product has been notified as a biocide in the Republic of Ireland in accordance with Statutory Instrument S. I. 625 of
2001. PCS Approval No. 93897
GUIDANCE NOTES
Occupational Exposure Limits EH40
HSE Guidance Booklet HS (G) 53: "The Selection, Use and Maintenance of Respiratory Protective Equipment - A Practical
Guide."
16 OTHER INFORMATION
The information contained in this safety data sheet is based on the present state of knowledge and current national
legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed
as any guarantee of technical performance or suitability for particular applications.
The product should not be used for purposes other than those shown in section 1 without first referring to the supplier and
obtaining written handling instructions. As the specific conditions of use of the product are outside the supplier's control,
the user is responsible for ensuring that the requirements of relevant legislation are complied with.
Read label before you buy. Use pesticides safely.
Use only in accordance with the directions on the label.
To avoid risks to man and the environment, comply with the instructions for use.
The [COSHH] Control of Substances Hazardous to Health Regulations may apply to the use of this product at work.
Engineering control of operator exposure must be used, where reasonably practicable, in addition to advice given on
personnel protective equipment. [Refer to Sections 8 and15]
However, engineering controls may replace personal protective equipment if a COSHH assessment shows that they
provide an equal or higher standard of protection.
Avoid excessive contamination of coveralls and launder regularly.
For specific guidance contact Ronseal Technical Services. [Helpline +44 (0) 114 240 9469 ] ; Email: [email protected].
uk
For further information on products available in the Republic of Ireland, contact Ronseal Ireland Ltd. Tel. +353 (0) 1 294
4009 ; Fax + 353 (0) 1 294 4016 ; Email [email protected]
REVISION COMMENTS
New product.
REVISION DATE
REV. NO./REPL. SDS
New issue
SAFETY DATA SHEET STATUS
Approved.
DATE
K. R. P. Winder.
REVISION DATE: 25-11-2004 RONSEAL TOTAL WOOD PRESERVER - CLEAR
RISK PHRASES IN FULL
R10
Harmful if swallowed.
May cause sensitisation by skin contact.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Harmful: may cause lung damage if swallowed.
Repeated exposure may cause skin dryness or cracking.
Information contained in this Safety Data Sheet is based on data considered to be accurate at the time of its preparation. Despite our efforts, it may not be up to date or applicable to the circumstances of any particular case. , The supplier accepts no responsibility whatsoever (except otherwise provided in law) for any damage or injury resulting from abnormal use, from any failure to follow appropriate practices or from hazards inherent in the product.

Source: http://www.tbsdirect.co.uk/dbdocument/3474/DR010545.pdf